Diffuse reflectance of short-fiber-reinforced composites aligned by an electric field

This study aims to characterize the translucency of aligned, short-fiber composites by determining the effects of filler particle orientation on the Kubelka-Munk absorption and scattering coefficients.

Rectangular composite specimens (n = 3) were filled with very short E-glass fibers. The fibers were oriented random, perpendicular, and parallel to the surface normal using an alternating electric field of 0.75 kV/mm. Diffuse reflectances of the composites on white and black backings were acquired with a spectrophotometer. The Kubelka-Munk model was then employed to calculate absorption and scattering coefficients.

The ordering of the reflectances on a white backing is neither the same nor the reverse of the reflectances on the black backing. The effects of orientation were different for the absorption and scattering coefficients. Orientation parallel to the average light flux notably decreases the amount of absorption, while perpendicular orientation appreciably increases the amount of scattering.

Since orientation affects the absorption and scattering coefficients differently, the ordering of the reflectances may be different when the backing is varied. This is because the translucency is composed of two parameters (absorption and scattering) and cannot be adequately summarized with one parameter such as transmittance or reflectance. Therefore, the use of a diffuse reflectance model, such as Kubelka-Munk, is essential to a quantitative understanding of the translucency effects of filler orientation. Understanding how the filler orientation affects diffuse reflectance of composites will yield insight as to how the orientation of enamel rods affects the diffuse reflectance in teeth by analogy.