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Dialkylaminopyridine-functionalized mesoporous silica nanosphere as an efficient and highly stable heterogeneous
Hung-Ting Chen1, Seong Huh, Jerzy W Wiench
1Department of Chemistry, Iowa State University, Ames, Iowa 50011-3111, USA.
Abstract:
A new nucleophilic catalytic system comprised of dialkylaminopyridine-functionalized mesoporous silica nanosphere (DMAP-MSN) has been synthesized and characterized. We have demonstrated that this material is an efficient heterogeneous catalyst for Baylis-Hillman, acylation, and silylation reactions with good reactivity, product selectivity, and recyclability. We envision that this DMAP-functionalized mesoporous silica material can also serve as an effective heterogeneous catalyst for many other catalytic nucleophilic reactions.
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