Dielectric spectroscopy of a binary mixture of liquid crystals showing wide temperature range twisted grain boundary phase with re-entrant cholesteric phase

There are only few materials, which have shown long temperature range twisted grain boundary (TGB) phases. One such material is the chiral binary mixture of 7OCB and 5* CBB (mole ratio 0.8 and 0.2) which shows unique phase sequence of cholesteric ( N*) , a wide temperature range TGBA (approximately 31 degrees C) and reentrant cholesteric (N*re) phases. In the present work we are reporting the dielectric spectroscopy of the above mixture with a chiral analog of earlier reported nematic (N) , smectic- A (SmA) , and reentrant nematic (Nre) phase sequences [Phys. Rev. A 46, 7733 (1992)] for different conditions of molecular orientations. Two modes of dielectric relaxations have been detected in a homeotropically aligned sample with unusually low relaxation frequencies for one of them. Planar oriented molecules in the TGBA phase show a soft mode of relaxation and support the recently proposed theory for the soft mode relaxation of the TGBA phase [Phys. Rev. E 65, 11701 (2001)]. By applying the dc electric field on planar oriented molecules in the TGBA phase, it has been possible to obtain a helix free homeotropically aligned TGBA phase.