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Updated: Aug 15, 2026

NMR 15N Relaxation Experiments for the Investigation of Picosecond to Nanoseconds Structural Dynamics of Proteins
Published on: November 1, 2024
Global and local relaxation of a spin chain under exact Schrödinger and master-equation dynamics
Markus J Henrich1, Mathias Michel, Michael Hartmann
1Institute of Theoretical Physics I, University of Stuttgart, Pfaffenwaldring 57, 70550 Stuttgart, Germany. henrich@theo1.physik.uni-stuttgart.de
Abstract:
We solve the Schrödinger equation for an interacting spin chain locally coupled to a quantum environment with a specific degeneracy structure. The reduced dynamics of the whole spin chain as well as of single spins is analyzed. We show that the total spin chain relaxes to a thermal equilibrium state independently of the internal interaction strength. In contrast, the asymptotic states of each individual spin are thermal for weak but nonthermal for stronger spin-spin coupling. The transition between both scenarios is found for couplings of the order of 0.1 x deltaE , with deltaE denoting the Zeeman splitting. We compare these results with a master-equation treatment; when time averaged, both approaches lead to the same asymptotic state and finally with analytical results.
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