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Practical synthesis of Dirhodium(II) tetrakis[N-phthaloyl-(S)-tert-leucinate]
Hideyuki Tsutsui1, Takumi Abe, Seiichi Nakamura
1Graduate School of Pharmaceutical Sciences, Hokkaido University, Sapporo, Japan.
Abstract:
An efficient and reliable procedure for the preparation of dirhodium(II) tetrakis[N-phthaloyl-(S)-tert-leucinate], Rh2(S-PTTL)(4), a universally effective catalyst for a range of enantioselective carbene transformations, is described. The N-phthaloylation of (S)-tert-leucine by the method of Bose with essentially no racemization is a key to this process.
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