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Updated: Aug 15, 2026

Amide Coupling Reaction for the Synthesis of Bispyridine-based Ligands and Their Complexation to Platinum as Dinuclear Anticancer Agents
Published on: May 28, 2014
Unassisted eta2-coordination of polycyclic aromatic hydrocarbons to platinum(II)
Jesús R Berenguer1, Juan Forniés, L Francisco Martín
1Instituto de Ciencia de Materiales de Aragón, Facultad de Ciencias, Universidad de Zaragoza-C.S.I.C., C/Pedro Cerbuna 12, E-50009 Zaragoza, Spain.
Abstract:
The coordination of phenanthrene to the d8 Pt(II) center in (SP-4-2)-[Pt(C6F5)2(CO)(eta2-C14H10)] causes a slight pyramidalization at the metal-bound C atoms (C9 and C10), but no perceptible elongation of the corresponding C-C bond [C(13)-C(14) 132.0(5) vs. 133.8(5) pm in the free ligand].
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