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Updated: Jul 6, 2026

Dynamic Pore-scale Reservoir-condition Imaging of Reaction in Carbonates Using Synchrotron Fast Tomography
Published on: February 21, 2017
A 'dry' condensation origin for circumstellar carbonates
Alice Toppani1, François Robert, Guy Libourel
1Centre de Recherches Pétrographiques et Géochimiques-CNRS UPR 2300, 15 rue Notre Dame des Pauvres, BP 20, Vandoeuvre-les-Nancy, France. toppani2@llnl.gov
Carbonate minerals, previously linked to water, can form abiogenically with silicates in space. This finding suggests new origins for cosmic carbonates in hot, dense stellar environments.
Area of Science:
- Astrochemistry
- Planetary Science
- Mineralogy
Background:
- Carbonate minerals are detected in astrophysical environments like protostars.
- Abiogenic carbonates typically indicate aqueous alteration with CO2-rich water.
- Recent detections in planetary nebulae and protostars challenge this indicator's relevance.
Purpose of the Study:
- To investigate an alternative formation pathway for astrophysical carbonates.
- To explore the role of non-equilibrium condensation in carbonate formation.
- To understand the origin of carbonates in environments lacking liquid water.
Main Methods:
- Experimental simulation of non-equilibrium condensation.
- Condensation of silicate gas in a H2O-CO2-rich vapor.
- Analysis of co-condensed amorphous silicates and carbonates.
Main Results:
- Demonstrated abiogenic formation of carbonates alongside amorphous silicates.
- Successful co-condensation occurred during non-equilibrium processes.
- Identified conditions favoring carbonate formation without liquid water.
Conclusions:
- Astrophysical carbonates may form via non-equilibrium condensation in space.
- Proposed formation sites include evolved stellar winds and protostellar outflows.
- This provides an alternative explanation for observed cosmic carbonates.
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