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A highly active catalyst for CO oxidation at 298 K: mononuclear AuIII complexes anchored to La2O3 nanoparticles
Juan C Fierro-Gonzalez1, Vinesh A Bhirud, Bruce C Gates
1Department of Chemical Engineering and Materials Science, University of California-Davis, Davis, CA 95616, USA.
Abstract:
Mononuclear La2O3-supported AuIII complexes synthesised from AuIII(CH3)2(C5H7O2) and characterised by X-ray absorption spectroscopy are highly active, stable CO oxidation catalysts at room temperature, demonstrating the importance of the support in stabilizing catalytically active gold species, which need not include zerovalent gold for high activity.
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