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Updated: Jul 9, 2026

Synthesis and Functionalization of Nitrogen-doped Carbon Nanotube Cups with Gold Nanoparticles as Cork Stoppers
Published on: May 13, 2013
Route to GaN and VN assisted by carbothermal reduction process
Huaizhou Zhao1, Ming Lei, Xin'an Yang
1Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, P.O. Box 603, Beijing 100080, PR China.
Abstract:
A route to prepare nitrides, such as GaN, VN, and other nitrides, is reported. The reaction pathway involves a two-step process by using the as-synthesized a-C3N3.69 as precursor. The route is so potent that a series of nitrides can be directly synthesized from their oxides at moderate temperatures. A striking feature of this method lies in that a-C3N3.69 is found to play double roles as both carbonizing and nitridizing agent in these reactions. These results will greatly deepen our understandings of the mechanism for solid-state metathesis reactions.
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