Rhodium-catalysed 1,4-addition of diarylindium hydroxides to alpha,beta-unsaturated carbonyl compounds
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Updated: Aug 14, 2026

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
Published on: June 21, 2017
Tomoya Miura1, Masahiro Murakami
1Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Kyoto, 615-8510, Japan.
Abstract:
Diarylindium(III) hydroxides react with alpha,beta-unsaturated carbonyl compounds in the presence of a rhodium catalyst to afford the 1,4-addition products in high yield. This reaction demonstrates the utility of diarylindium(III) hydroxide as an aryl source with rhodium catalysts.
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