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Published on: August 10, 2017
Multifunctional cadmium single source precursor for the selective deposition of CdO or CdS by a solution route
Graziella Malandrino1, Sebastiana T Finocchiaro, Patrizia Rossi
1Dipartimento di Scienze Chimiche, Università di Catania and INSTM, UdR Catania, V.le Andrea Doria 6, I-95125, Catania, Italy. gmalandrino@dipchi.unict.it
Summary
Researchers developed a novel precursor, Cd(tta)2 x tmeda, for creating high-quality cadmium sulfide (CdS) or cadmium oxide (CdO) films. This simple solution process allows for selective and reproducible film fabrication.
Area of Science:
- Materials Science
- Inorganic Chemistry
- Nanotechnology
Background:
- Thin film deposition is crucial for various electronic and optical applications.
- Developing cost-effective and reproducible methods for high-quality film fabrication remains a challenge.
- Cadmium-based materials like CdS and CdO are important semiconductors with diverse applications.
Purpose of the Study:
- To introduce a novel single precursor, Cd(tta)2 x tmeda, for cadmium-based thin film deposition.
- To demonstrate the selective and reproducible fabrication of pure quality CdS and CdO films.
- To highlight the advantages of a simple solution process for material synthesis.
Main Methods:
- Synthesis of the novel single precursor: Cd(tta)2 x tmeda, where Htta is 2-thenoyl-trifluoroacetone and tmeda is N,N,N',N'-tetramethylethylenediamine.
- Utilizing a simple solution process for thin film fabrication.
- Characterization of the fabricated CdS and CdO films to confirm purity and quality.
Main Results:
- The precursor Cd(tta)2 x tmeda enables selective fabrication of either CdS or CdO films.
- High-quality and pure films of CdS and CdO were reproducibly obtained.
- The solution process proved to be simple and effective for thin film deposition.
Conclusions:
- The novel precursor Cd(tta)2 x tmeda is highly effective for controlled CdS and CdO thin film synthesis.
- The developed solution process offers a selective, reproducible, and high-quality method for fabricating cadmium-based films.
- This work provides a promising route for the scalable production of CdS and CdO thin films for technological applications.

