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Updated: Aug 14, 2026

Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks
Published on: February 10, 2023
Reaction growth of MF2/a-C (M = Ca, Mg) core/shell nanowires at the interface of vapor and solid reactants
Chih-Hao Huang1, Yu-Hsu Chang, Chi-Young Lee
1Department of Applied Chemistry, National Chiao Tung University, Hsinchu, Taiwan 30050, R.O.C
Abstract:
C(6)F(6) vapor is employed to react with CaC(2) and Mg(3)N(2) to grow CaF(2)/a-C and Mg(2)F(2)/a-C core/shell nanowires (tens of micrometers in length, tens to hundreds of nanometers in wire diameter, and tens of nanometers in core diameter), respectively, in high yields. The growth mechanism is proposed to proceed via a reaction at the interface of the vapor and solid reactants.
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