Critical adsorption at silicon surfaces in binary liquid mixtures

In critical binary liquid mixtures the preferential adsorption that occurs at liquid-vapor or liquid-solid surfaces is expected to be described by a universal surface scaling function. In this paper, we show that aniline strongly adsorbs at an oxide-coated Si wafer surface from a critical mixture of aniline + cyclohexane where this solid-liquid adsorption can be described by the same universal function found at liquid-vapor surfaces. For a tetrabromoethane + n-dodecane critical mixture the n-dodecane adsorption on an alkylsilane coated Si wafer cannot be described by previously determined adsorption functions. We speculate that this discrepancy is caused by chemical heterogeneities at the alkylsilane surface due to differing surface distributions of -CH3 and -CH2- groups within the silane layer.