Surface transport in premelted films with application to grain-boundary grooving

We present a new model of surface transport in premelted films that is applicable to a wide range of materials close to their melting points. We illustrate its use by applying it to the evolution of a grain-boundary groove in a high vapor pressure material and show that Mullins's classical equation describing transport driven by gradients in surface curvature is reproduced asymptotically. The microscopic contact angle at the groove root is found to be modified over a thin boundary layer, and the apparent contact angle is determined. An explicit transport coefficient is derived that governs the evolution rate of systems controlled by surface transport through premelted films. The transport coefficient is found to depend on temperature and diverges as the bulk melting temperature is approached.