Nonequilibrium dynamics of correlated electron transfer in molecular chains

The relaxation dynamics of correlated electron transport along molecular chains is studied based on a substantially improved numerically exact path integral Monte Carlo approach. As an archetypical model, we consider a Hubbard chain containing two interacting electrons coupled to a bosonic bath. For this generalization of the ubiquitous spin-boson model, non-Boltzmann equilibrium distributions are found for many-body states. By mapping the multiparticle dynamics onto an isomorphic single particle motion, this phenomenon is shown to be sensitive to particle statistics and, due to its robustness, allows for new control schemes in designed quantum aggregates.