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An octanuclear complex containing the [Fe3O]7+ metal core: structural, magnetic, Mössbauer, and electron paramagnetic

Athanassios K Boudalis1, Yiannis Sanakis, Françoise Dahan

  • 1Laboratoire de Chimie de Coordination du CNRS, UPR 8241, Toulouse, France. tbou@ims.demokritos.gr

Inorganic Chemistry
|January 5, 2006
PubMed
Summary

Researchers synthesized a novel iron(III) cluster with a [Fe(3)O](7+) core, revealing antiferromagnetic coupling and an S=1/2 ground state. Spectroscopic and magnetic studies confirmed these properties, including antisymmetric exchange interactions.

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