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Quantum transport in chains with noisy off-diagonal couplings.
Andrey Pereverzev1, Eric R Bittner
1Department of Chemistry, University of Houston, Houston, Texas 77204, USA.
The Journal of Chemical Physics
|January 7, 2006
Summary
This study models conductivity and energy diffusion in a linear chain, showing noise-averaged equations simplify to the Lindblad equation. Results demonstrate discrete heat and diffusion equations for energy and number densities.
Area of Science:
- Condensed Matter Physics
- Statistical Mechanics
- Quantum Dynamics
Background:
- Understanding transport phenomena in low-dimensional systems is crucial.
- Modeling energy and charge transport often involves complex Hamiltonians and noise effects.
- The Liouville-von Neumann equation describes system evolution but can be challenging to solve with noise.
Purpose of the Study:
- To develop a model for conductivity and energy diffusion in a linear chain system.
- To analyze the impact of Gaussian noise on system dynamics.
- To derive simplified equations of motion and identify transport coefficients.
Main Methods:
- Formulation of a quadratic Hamiltonian model with Gaussian noise.
- Derivation of the noise-averaged Liouville-von Neumann equation.
- Analysis of the system's density matrix for expectation values.
- Investigation of discrete heat and diffusion equations.
Main Results:
- The noise-averaged Liouville-von Neumann equation simplifies to the Lindblad equation under specific conditions (diagonal correlation matrix).
- Expectation values of energy and number densities satisfy discrete heat and diffusion equations.
- Transport coefficients are expressed via Hamiltonian parameters.
- Conditions for constant total energy and linear energy density gradients in heat reservoirs are discussed.
Conclusions:
- The model provides a framework for studying transport in noisy linear chains.
- The reduction to the Lindblad equation offers a more tractable approach for analysis.
- The derived discrete equations offer insights into heat and diffusion processes at a microscopic level.