Determination of the space-charge field amplitude in polymeric photorefractive polymers

The space-charge field built in a polymeric photorefractive polymer was calculated by a simple method based on the oriented gas model. When anisotropic chromophores in a photorefractive polymer were exposed to an external field, they oriented preferentially to exhibit a birefringence. Then, under illumination of two coherent beams and an external field, they reoriented to form a photorefractive grating. During the formation of the grating, the chromophores were reoriented by the space-charge field as well as by the external applied field. The birefringence induced in the material by an external electric field was determined by measuring the transmittance of the sample which is placed between crossed polarizers, where birefringence depicts the orientation of the chromophores. By measuring the diffraction efficiency with a modified degenerate four-wave mixing setup, the index amplitude of the grating was determined. Finally, the space-charge field was determined by comparing the diffraction efficiency with the birefringence with respect to the applied electric field. In our study, the space-charge field was about 20% of the external applied field, which coincided with previous results obtained from our laboratory.