Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

Thioamide pincer ligands with charge versatility.

Rowshan Ara Begum1, Douglas Powell, Kristin Bowman-James

  • 1Department of Chemistry, University of Kansas, 1251 Wescoe Hall Drive, Lawrence, Kansas 66045, USA.

Inorganic Chemistry
|January 31, 2006
PubMed
Summary
This summary is machine-generated.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Erratum to "Yeast cells experience chronological life span extension under prolonged glucose starvation" [Heliyon Volume 11, Issue 4, February 2025, Article e42898].

Heliyon·2025
Same author

An Allergy-Based Approach to Orofacial Granulomatosis: A Narrative Review.

Dermatitis : contact, atopic, occupational, drug·2025
Same author

Yeast cells experience chronological life span extension under prolonged glucose starvation.

Heliyon·2025
Same author

The association between skin allergy testing and oral squamous cell carcinoma in oral lichen planus: a retrospective cohort study.

Archives of dermatological research·2025
Same author

NASC 2023: Showcasing Diversity in North American Supramolecular Chemistry.

Supramolecular chemistry·2024
Same author

Drug-Induced dermatomyositis following COVID-19 vaccination.

Dermatology online journal·2024
Same journal

Hydrogen-Bond-Directed Assembly of Polyanionic Cluster [Mo<sub>2</sub>O<sub>5</sub>(IO<sub>3</sub>)<sub>4</sub>]<sup>2-</sup> for Nonlinear Optical Crystal Design.

Inorganic chemistry·2026
Same journal

Synthesis and Reactivity of Boron Triflate and Bistriflimide Complexes Bearing Two <i>ortho</i>-Carboranes.

Inorganic chemistry·2026
Same journal

Switchable Fluorescence of a Three-Dimensional Coordination Polymer Based on Reversible Single-Crystal to Single-Crystal Photoreaction.

Inorganic chemistry·2026
Same journal

8-Aminoquinoline Pendant Ligand-Driven Proton Shuttling in Copper Electrocatalysis for Enhanced Proton Reduction into Hydrogen Gas.

Inorganic chemistry·2026
Same journal

Observation of Structural and Electronic Transitions in Bimetallic Chalcogenide of Copper Tantalum Trisulfide via Pressure Engineering.

Inorganic chemistry·2026
Same journal

Theoretical Structure Prediction and High-Pressure Synthesis of a Layered Sodium Silicide Zintl Phase: Na<sub>2</sub>Si<sub>3</sub>.

Inorganic chemistry·2026
See all related articles

This study synthesizes palladium and platinum complexes with versatile thioamido ligands. Palladacycle I demonstrated superior performance as a Heck catalyst, showing enhanced catalytic activity.

Area of Science:

  • Coordination Chemistry
  • Organometallic Chemistry
  • Catalysis

Background:

  • Thioamido ligands offer tunable electronic properties through proton abstraction.
  • Palladium and platinum complexes are crucial in homogeneous catalysis.
  • The Heck reaction is a vital carbon-carbon bond-forming process.

Purpose of the Study:

  • Synthesize and characterize novel palladium and platinum complexes.
  • Investigate the charge versatility of 2,6-bis-thioamido-phenyl and 2,6-bis-thioamido-pyridine ligands.
  • Evaluate the catalytic activity of the synthesized complexes in the Heck reaction.

Main Methods:

  • Synthesis of metal complexes via established organometallic routes.
  • Characterization using spectroscopic techniques (NMR, IR, Mass Spectrometry).

Related Experiment Videos

  • X-ray crystallography for structural elucidation.
  • Catalytic testing in the Heck reaction.

    • Main Results:

    • Successfully synthesized two palladium and one platinum complex.
    • Demonstrated internal charge versatility in ligands via deprotonation.
    • Palladacycle I exhibited higher catalytic efficiency in the Heck reaction compared to other complexes.
    • Crystal structures of the synthesized complexes were determined.

    Conclusions:

    • The synthesized thioamido complexes show promise in catalysis.
    • Palladacycle I is an effective catalyst for the Heck reaction.
    • Ligand design influences catalytic performance in organometallic catalysis.