Soil desiccation rate integration into empirical dust emission models for polymer suppressant evaluation

Dust constitutes an environmental and human health menace in many regions of the world. The rate of soil desiccation is a significant determinant of the availability of fine soil particles for entrainment in air as dust. Dust suppressants such as polymer solutions can reduce soil desiccation rate, thereby reducing dust emission factor. Herein, a dust emission estimation methodology that involves the integration of desiccation time curves to find the average desiccation rate is formulated. This is combined with soil characteristics, stressor (environmental and possibly vehicle) characteristics and liquid content in soil to estimate potential emission factors. Using this methodology, the dust suppression potential of aqueous polyethylene oxide (PEO) solution was investigated experimentally with Na-montmorillonite (Na-mmt) as the model dust-generating material. PEO with a molecular weight of 8 x 10(6) and at aqueous concentrations ranging from 0.5 to 10 g/L, was mixed with 10 g of Na-mmt (surface area=31.82+/-0.22 m2/g) and desiccated for 700 h in a specially designed chamber at 25 degrees C and 30% relative humidity. The results show that generally, aqueous PEO is superior to distilled water as a dust suppressant for Na-mmt at concentrations in the range of 0.5-2.0 g/L. The experimental data obtained are introduced into the formulated estimation methodology, and potential emissions of dust from PEO-admixed Na-mmt are determined.