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Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
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Dichloro(1,2-dimethoxyethane)bis(tosylimido)molybdenum(VI), a versatile nitrene transfer reagent

Konstantin A Rufanov1, Burkhard Ziemer

  • 1Institut für Chemie, Humboldt-Universität zu Berlin, Brook-Taylor-Strasse 2, D-12489 Berlin, Germany. k_rufanov@gmx.de

Acta Crystallographica. Section C, Crystal Structure Communications
|February 4, 2006
PubMed
Summary

This study details a novel molybdenum complex with exceptionally short Mo-Cl bonds, enhancing its Lewis acidity. This characteristic makes it a versatile reagent for nitrene transfer reactions, useful in synthesizing new compounds.

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