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Published on: November 30, 2012
Optical intensity gradient by colloidal photonic crystals with a graded thickness distribution
1State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Graduate School of the Chinese Academy of Sciences, 5625 Renmin Street, Changchun 130022, PR China.
Langmuir : the ACS Journal of Surfaces and Colloids
|February 8, 2006
Summary
Gradient colloidal crystals with tunable thickness were created using vertical deposition. Their thickness gradient controls optical transmission intensity, offering potential for optical devices.
Area of Science:
- Materials Science
- Optics
- Nanotechnology
Background:
- Colloidal crystals are periodic structures with unique optical properties.
- Controlling the thickness of colloidal crystals is crucial for tuning their optical response.
Purpose of the Study:
- To prepare gradient colloidal crystals with a thickness gradient.
- To investigate the relationship between thickness gradient and optical transmission.
- To explore the potential applications of these gradient structures.
Main Methods:
- Vertical deposition technique using vertically graded concentration suspensions.
- Preparation of colloidal crystals with a gradual change in thickness along a specific direction.
- Analysis of optical transmission intensity at the dip wavelength.
Main Results:
- Successfully fabricated gradient colloidal crystals with a thickness gradient.
- Demonstrated that the thickness gradient is determined by the initial colloidal concentration and settling time.
- Showed that optical transmission intensity at the dip wavelength can be tuned by adjusting crystal thickness.
- Observed a gradient of optical intensity at the dip in transmission light, which increases with the thickness gradient.
Conclusions:
- Gradient colloidal crystals can be fabricated by controlling suspension concentration and settling time.
- The thickness gradient directly influences the optical intensity gradient.
- These gradient colloidal crystals offer tunable optical properties for potential applications in optical devices.

