Mechanistic insights into NO3* induced self-terminating radical oxygenations, part 1: a computational study on NO3*...

The geometry of the nitrate radical, NO3*, for which unrestricted Hartree-Fock (HF) breaks spatial symmetry of the wave function, was optimized using hybrid density functionals that include varying fractions of Hartree-Fock exchange. Although symmetry breaking was not observed even when the functional with the highest HF exchange (BHandHLYP) was used, only B3LYP correctly describes the D(3h) symmetry of NO3* as ground-state structure with the lowest energy. Further, geometries and energies of the stationary points in the addition of NO3* to ethyne, propyne, and 2-butyne were calculated using ab initio and density functional methods. The reactions proceed through Z-configurated transition states leading to Z-configurated vinyl radicals with the activation barrier decreasing with increasing methyl substitution at the C[triple bond]C by ca. 11 kJ mol(-1) per methyl group. It was found that the results obtained at the BHandHLYP/cc-pVDZ level of theory are in good agreement with the data from single-point QCISD and CCSD(T) calculations.