Related Experiment Video
Updated: Aug 11, 2026

08:22
Measurement of Ultrafast Vibrational Coherences in Polyatomic Radical Cations with Strong-Field Adiabatic Ionization
Published on: August 6, 2018
Double excitations of helium in weak static electric fields
Conny Såthe1, Magnus Ström, Marcus Agåker
1Physics Department, Box 530, S-751 21 Uppsala, Sweden.
Physical Review Letters
|February 21, 2006
Summary
Electric fields dramatically alter helium
Area of Science:
- Atomic physics
- Quantum mechanics
- Spectroscopy
Background:
- Doubly excited states in helium exhibit complex behavior.
- Electric field effects on atomic spectra are crucial for understanding quantum phenomena.
Purpose of the Study:
- Investigate the electric field dependence of fluorescence yield in helium's doubly excited states.
- Explain the observed spectral features, including yield tuning and enhancement of forbidden states.
Main Methods:
- Employed R-matrix multichannel quantum defect theory.
- Utilized spherical-to-parabolic frame transformation.
Main Results:
- Successfully reproduced key features of the experimental fluorescence yield spectrum.
- Observed dramatic electric field dependence below the ionization threshold.
- Tuned fluorescence yields to zero for specific states.
- Significantly enhanced dipole-forbidden states with weak electric fields (< 1 kV/cm).
Conclusions:
- Weak electric fields induce significant mixing of states in helium.
- The theoretical model accurately captures the observed spectral phenomenology.
- Provides insights into the quantum behavior of atoms under external fields.
Related Concept Videos
Electric Field of Two Equal and Opposite Charges
Atoms generally contain the same number of positively and negatively charged particles, protons, and electrons. Hence, they are electrically neutral. However, the centers of the positive and negative charges do not always coincide. In such a scenario, the electric field of an atom may not be zero.
A separation of the positive and negative charges can lead to a weak, remnant effect of the positive and negative charges. The expectation is that the more the distance between the positive and...
A separation of the positive and negative charges can lead to a weak, remnant effect of the positive and negative charges. The expectation is that the more the distance between the positive and...
Atomic Nuclei: Nuclear Relaxation Processes
In the absence of an external magnetic field, nuclear spin states are degenerate and randomly oriented. When a magnetic field is applied, the spins begin to precess and orient themselves along (lower energy) or against (higher energy) the direction of the field. At equilibrium, a slight excess population of spins exists in the lower energy state. Because the direction of the magnetic field is fixed as the z-axis, the precessing magnetic moments are randomly oriented around the z-axis. This...
Induced Electric Dipoles
A permanent electric dipole orients itself along an external electric field. This rotation can be quantified by defining the potential energy because the external torque does work in rotating it. Then, the potential energy is minimum at the parallel configuration and maximum at the antiparallel configuration. While the former is a stable equilibrium, the latter is an unstable equilibrium.
Since the absolute value of potential energy holds no physical meaning, its zero value can be chosen as per...
Since the absolute value of potential energy holds no physical meaning, its zero value can be chosen as per...
Spin–Spin Coupling Constant: Overview
In bromoethane, the three methyl protons are coupled to the two methylene protons that are three bonds away. In accordance with the n+1 rule, the signal from the methyl protons is split into three peaks with 1:2:1 relative intensities. The methylene protons appear as a quartet, with the relative intensities of 1:3:3:1.
Qualitatively, any spin plus-half nucleus polarizes the spins of its electrons to the minus-half state. Consequently, the paired electron in the hydrogen–carbon bond must have a...
Qualitatively, any spin plus-half nucleus polarizes the spins of its electrons to the minus-half state. Consequently, the paired electron in the hydrogen–carbon bond must have a...
Atomic Nuclei: Nuclear Spin State Population Distribution
Near absolute zero temperatures, in the presence of a magnetic field, the majority of nuclei prefer the lower energy spin-up state to the higher energy spin-down state. As temperatures increase, the energy from thermal collisions distributes the spins more equally between the two states. The Boltzmann distribution equation gives the ratio of the number of spins predicted in the spin −½ (N−) and spin +½ (N+) states.
Electrostatic Boundary Conditions in Dielectrics
When an electric field passes from one homogeneous medium to another, crossing the boundary between the two mediums imparts a discontinuity in the electric field. This results in electrostatic boundary conditions that depend on the type of mediums the field propagates through.
Consider a case where both the mediums across a boundary are two different dielectric materials. Recall that the electric field and electric displacement are proportional and related through the material's permittivity.
Consider a case where both the mediums across a boundary are two different dielectric materials. Recall that the electric field and electric displacement are proportional and related through the material's permittivity.

