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Amide Coupling Reaction for the Synthesis of Bispyridine-based Ligands and Their Complexation to Platinum as Dinuclear Anticancer Agents
Published on: May 28, 2014
Porphyrin dimers bridged by a platinum-diacetylide unit
Yi-Jen Chen1, Szu-Shuo Chen, Shang-Shih Lo
1Department of Chemistry, National Chung Hsing University, Taichung 402, Taiwan.
Abstract:
A series of butadiyne- and platinum diacetylide-bridged conjugated porphyrin dimers have been prepared; electrochemical and UV-vis absorption measurements on these compounds show that the butadiyne-bridge confers stronger porphyrin-porphyrin conjugation than the platinum diacetylide-bridge.
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