Substrate induced 1D tilt-modulated state in nematic monolayers

Symmetry considerations yield the general form, up to second order terms, for the deformation elastic energy of a nematic monolayer, composed by symmetric achiral molecules, on a rigid planar substrate. The deformation energy contains an elastic contribution linear in the deformation tensor, whose elements are the spatial derivatives of the average molecular orientation. This linear Lifshitz-invariant-like term can be responsible for a ground state of the nematic monolayer periodically deformed if the relevant elastic constant is stiffer than a critical value. The wave-length of the modulation diverges at the transition threshold. We show that only large variations of the tilt angle form stable states. The effect of a destabilizing electric or magnetic field on the layer is to induce (i) the transition towards the tilt-modulated phase, while (ii) for higher enough values of the field the modulation is destroyed.