Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Electron Affinity03:07

Electron Affinity

The electron affinity (EA) is the energy change for adding an electron to a gaseous atom to form an anion (negative ion).
Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions.
Lewis Structures of Molecular Compounds and Polyatomic Ions02:54

Lewis Structures of Molecular Compounds and Polyatomic Ions

To draw Lewis structures for complicated molecules and molecular ions, it is helpful to follow a step-by-step procedure as outlined:
Molecular and Ionic Solids02:54

Molecular and Ionic Solids

Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
Ionic Crystal Structures02:42

Ionic Crystal Structures

Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Imperfections in Crystal Structure: Stoichiometric Point Defects01:26

Imperfections in Crystal Structure: Stoichiometric Point Defects

Schottky defects arise when some lattice points in a crystal, such as those in NaCl, remain unoccupied, creating lattice vacancies without disturbing the overall electrical neutrality of the crystal. This defect is common in ionic crystals where the positive and negative ions are similar in size, as seen in sodium chloride and cesium chloride. The presence of Schottky defects enables the crystal to conduct electricity to a small extent through an ionic mechanism. Electric fields cause nearby...

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

[Simultaneous determination of twelve sulfonyl urea herbicide residues in rice by high performance liquid chromatography with solid-phase extraction].

Se pu = Chinese journal of chromatography·2006
Same author

High rate of chimeric gene origination by retroposition in plant genomes.

The Plant cell·2006
Same author

Enzyme catalysis: tool to make and break amygdalin hydrogelators from renewable resources: a delivery model for hydrophobic drugs.

Journal of the American Chemical Society·2006
Same author

Theoretical probing of deltahedral closo-auroboranes B(x)Au(x)2- (x = 5-12).

Inorganic chemistry·2006
Same author

Density functional theory/time-dependent DFT studies on the structures, trend in DNA-binding affinities, and spectral properties of complexes [Ru(bpy)2(p-R-pip)]2+ (R = -OH, -CH3, -H, -NO2).

The journal of physical chemistry. A·2006
Same author

Sn12(2-): stannaspherene.

Journal of the American Chemical Society·2006

Related Experiment Video

Updated: Jul 6, 2026

Hyperpolarized Xenon for NMR and MRI Applications
16:20

Hyperpolarized Xenon for NMR and MRI Applications

Published on: September 6, 2012

Formation and characterization of the XeOO(+) cation in solid argon.

Mingfei Zhou1, Yanying Zhao, Yu Gong

  • 1Department of Chemistry & Laser Chemistry Institute, Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Fudan University, China. mfzhou@fudan.edu.cn

Journal of the American Chemical Society
|February 24, 2006
PubMed
Summary

Researchers prepared and characterized a novel xenon-containing cationic radical, XeOO+. This new species exhibits a stable, bent structure with direct xenon-oxygen bonding, offering insights into noble gas chemistry.

More Related Videos

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
06:44

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding

Published on: March 24, 2018

Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
06:53

Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks

Published on: June 9, 2023

Related Experiment Videos

Last Updated: Jul 6, 2026

Hyperpolarized Xenon for NMR and MRI Applications
16:20

Hyperpolarized Xenon for NMR and MRI Applications

Published on: September 6, 2012

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
06:44

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding

Published on: March 24, 2018

Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
06:53

Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks

Published on: June 9, 2023

Area of Science:

  • Inorganic Chemistry
  • Physical Chemistry
  • Quantum Chemistry

Background:

  • Noble gases, traditionally considered inert, are increasingly being incorporated into novel chemical species.
  • Understanding the bonding and stability of xenon compounds is crucial for exploring new chemical frontiers.

Purpose of the Study:

  • To synthesize and characterize a xenon- and oxygen-containing cationic radical, XeOO+.
  • To investigate the structural and electronic properties of the XeOO+ species.
  • To determine the energetic stability of XeOO+ relative to its constituent reactants.

Main Methods:

  • Co-deposition of laser ablated transition metals with O2/Xe mixtures in excess Ar.
  • Condensation of high-frequency discharged O2/Xe/Ar mixtures at cryogenic temperatures (12 K).
  • Identification using infrared (IR) spectroscopy and high-level quantum chemical calculations.

Main Results:

  • Successful synthesis and characterization of the XeOO+ cation.
  • Experimental identification via unique infrared absorptions.
  • Quantum chemical calculations revealed a bent structure with direct xenon-oxygen dative bonding.
  • The doublet ground state of XeOO+ was found to be significantly more stable than Xe + O2+.

Conclusions:

  • The study demonstrates the feasibility of creating stable xenon-oxygen cationic species.
  • The findings provide direct evidence for xenon-oxygen dative bonding in XeOO+.
  • XeOO+ represents a novel, stable molecule expanding the known chemistry of noble gases.