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Ammonium O,O-dicyclohexyl phosphorodithioate.

Mustafa Serkan Soylu1, Mehtap Yağan, Nezihe Calişkan

  • 1Department of Physics, Giresun Faculty of Arts and Sciences, Karadeniz Technical University, 28100 Giresun, Turkey. mssoylu@omu.edu.tr

Acta Crystallographica. Section C, Crystal Structure Communications
|March 7, 2006
PubMed
Summary
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Ammonium and O,O-dicyclohexyl phosphorodithioate form a polymer via hydrogen bonds. This structure creates layered sheets, revealing new insights into crystal engineering and material science.

Area of Science:

  • Crystal chemistry
  • Materials science
  • Supramolecular chemistry

Background:

  • Understanding the self-assembly of ionic compounds is crucial for designing novel materials.
  • Phosphorodithioate anions offer versatile coordination capabilities due to their heteroatoms.

Purpose of the Study:

  • To elucidate the crystal structure of the ammonium salt of O,O-dicyclohexyl phosphorodithioate.
  • To investigate the intermolecular interactions governing the compound's assembly.

Main Methods:

  • Single-crystal X-ray diffraction was employed to determine the three-dimensional structure.
  • Analysis of hydrogen bonding networks (N-H...O and N-H...S) was performed.

Main Results:

  • The compound exhibits a polymeric structure composed of ammonium cations and O,O-dicyclohexyl phosphorodithioate anions.

Related Experiment Videos

  • Hydrogen bonds between the ammonium and phosphorodithioate moieties link the components into extended (100) sheets.
  • The crystal packing is dominated by these specific hydrogen bonding interactions.

    • Conclusions:

    • The study reveals a novel polymeric sheet structure driven by N-H...O and N-H...S hydrogen bonds.
    • This detailed structural analysis provides a foundation for predicting and synthesizing related phosphorodithioate materials.
    • The findings contribute to the broader understanding of hydrogen bonding in the construction of extended solid-state architectures.