Uniquely strong electronic communication between [Mo2] units linked by dioxolene dianions.

F Albert Cotton1, Carlos A Murillo, Dino Villagrán

  • 1Department of Chemistry and Laboratory for Molecular Structure and Bonding, Texas A&M University, P.O. Box 30012, College Station, Texas 77842-3012, USA. cotton@tamu.edu

Summary

Strong electronic communication was observed in dimolybdenum compounds linked by dioxolene anions. This interaction facilitates significant charge delocalization in mixed-valence species, confirmed by structural and spectroscopic analyses.

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