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Dissociative electron attachment in selected haloalkanes

S A Pshenichnyuk1, I A Pshenichnyuk, E P Nafikova

  • 1Institute of Physics of Molecules and Crystals, October Prospect 151, Ufa 450075, Russia.

Rapid Communications in Mass Spectrometry : RCM
|March 9, 2006
PubMed

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Halogenation is another class of electrophilic addition reactions where a halogen molecule gets added across a π bond. In alkynes, the presence of two π bonds allows for the addition of two equivalents of halogens (bromine or chlorine). The addition of the first halogen molecule forms a trans-dihaloalkene as the major product and the cis isomer as the minor product. Subsequent addition of the second equivalent yields the tetrahalide.
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Electrophilic Addition to Alkynes: Hydrohalogenation

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Multiple Halogenation of Methyl Ketones: Haloform Reaction

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