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Updated: Aug 9, 2026

Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)
Published on: November 22, 2016
[P6Se12]4-: a phosphorus-rich selenophosphate with low-valent P centers
In Chung1, Angela L Karst, David P Weliky
1Department of Chemistry, Michigan State University, East Lansing, Michigan 48824, USA.
Abstract:
The new selenophosphate Rb4P6Se12 features the trans-decalin-like, [P6Se12]4- anion, a phosphorus-rich species that possesses three parallel P-P bonds and formally P2+ and P4+ centers. The synthesis of Rb4P6Se12 was accomplished with the reductive addition of P to RbPSe6 and represents an interesting example of how alkali chalcophosphates can serve as starting materials to produce new compounds under mild reaction conditions.
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