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Updated: Jun 10, 2026

Preparation of Highly Porous Coordination Polymer Coatings on Macroporous Polymer Monoliths for Enhanced Enrichment of Phosphopeptides
Published on: July 14, 2015
Immobilization of sodium ions on the pore surface of a porous coordination polymer
Satoshi Horike1, Ryotaro Matsuda, Daisuke Tanaka
1Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Japan.
Abstract:
A porous coordination polymer (PCP) with immobilization of sodium cations on the pore surface has been synthesized, by employing a bifunctional carboxylate/sulfonate ligand, and structurally characterized. The porous framework with 1D channels of the dimension of 4.9 x 4.9 A2 shows high thermal stability ( approximately 330 degrees C), affording Type I adsorption isotherms for CO2, acetone, and benzene. The chemical shift of 13C NMR and characteristic adsorption energy (betaE0) of acetone adsorbed in this compound represent the Lewis acidity of this framework.
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