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Crystallography of new ternary borides
1Bell Laboratories, Murray Hill, New Jersey 07974.
Summary
New ternary rhodium borides structures were determined. These compounds show isomorphism with known ternary cobalt borides, indicating similar crystal structures.
Area of Science:
- Materials Science
- Inorganic Chemistry
- Solid-State Chemistry
Background:
- Ternary borides are compounds containing three elements, including boron.
- Understanding the crystal structures of new materials is crucial for predicting their properties.
- Rhodium and cobalt borides are of interest due to their potential applications.
Purpose of the Study:
- To determine the crystal structure of newly synthesized ternary rhodium borides.
- To investigate the relationship between ternary rhodium borides and ternary cobalt borides.
Main Methods:
- Crystallographic analysis was employed to determine the atomic arrangement.
- Powder X-ray diffraction (PXRD) was used for structural characterization.
Main Results:
- The crystal structures of several new ternary rhodium borides were successfully elucidated.
- Isomorphism was established between the determined rhodium borides and their cobalt counterparts.
Conclusions:
- The new ternary rhodium borides adopt structures analogous to those of ternary cobalt borides.
- This structural similarity suggests potential parallels in their physical and chemical properties.
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