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Stochastic Model of Unimolecular Reactions and the RRKM Theory
S H Lin1, K H Lau, W Richardson
1Department of Chemistry, Arizona State University, Tempe, Arizona 85281.
Abstract:
A stochastic model of unimolecular reactions has been adopted for investigation of the validity and limitation of the RRKM theory. The error caused by the steady-state approximation for distribution of energized molecules is small, while the assumption of the internal energy equilibration of energized molecules might cause serious errors for reactions of low activation energies.
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