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Updated: Aug 9, 2026

Spin Saturation Transfer Difference NMR (SSTD NMR): A New Tool to Obtain Kinetic Parameters of Chemical Exchange Processes
Published on: November 12, 2016
On spin-exchange and electron-transfer rates in bacterial photosynthesis
R Haberkorn1, M E Michel-Beyerle, R A Marcus
1Institut für Physikalische und Theoretische Chemie, Technische Universität Munchen, D-8046 Garching, West Germany.
Abstract:
A discrepancy is explored regarding the spin exchange integral estimated from magnetic field effects on recombination of the bacteriochlorophyll dimer cation (Bchl)(2)+ and the bacteriopheophytin anion Bph(-) and the measured electron transfer rate between Bph and electronically excited (Bchl)(2). In one explanation considered here there are two sites for the electron or for the hole, with a hopping between sites.
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