[NaCu(II)4] cluster from alkali template assembly of two asymmetric end-on azido-bridged [Cu(II)2] units

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Prasant Kumar Nanda1, Guillem Aromí, Debashis Ray

  • 1Department of Chemistry, Indian Institute of Technology, Kharagpur 721 302, India.

Inorganic Chemistry
|April 11, 2006
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Structural Isomerism02:34

Structural Isomerism

Isomerism in Complexes
Isomers are different chemical species that have the same chemical formula. Structural isomerism of coordination compounds can be divided into two subcategories, the linkage isomers and coordination-sphere isomers.
Linkage isomers occur when the coordination compound contains a ligand that can bind to the transition metal center through two different atoms. For example, the CN− ligand can bind through the carbon atom or through the nitrogen atom. Similarly, SCN− can be...