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Regioselective O-Glycosylation of Nucleosides via the Temporary 2',3'-Diol Protection by a Boronic Ester for the Synthesis of Disaccharide Nucleosides
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A convenient gram-scale synthesis of uridine diphospho(13C6)glucose

Zoran Dinev1, Ahmad Z Wardak, Robert T C Brownlee

  • 1School of Chemistry, University of Melbourne, Parkville, Victoria 3010, Australia.

Carbohydrate Research
|April 11, 2006
PubMed

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Polysaccharides such as glycogen and starch are synthesized from nucleoside diphosphate sugars, primarily uridine diphosphate glucose (UDPG) and adenosine diphosphate glucose (ADPG). These activated glucose donors act as key intermediates in carbohydrate metabolism and biosynthesis. UDPG primarily involves glycogen synthesis in animals and many bacteria, while ADPG plays a fundamental role in starch synthesis in plants and certain bacteria.UDPG is formed when glucose-1-phosphate reacts with...