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Updated: Aug 9, 2026

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
Published on: July 27, 2022
Risk of misinterpretation of nearly degenerate pair bands as chiral partners in nuclei
C M Petrache1, G B Hagemann, I Hamamoto
1Dipartimento di Fisica, Università di Camerino and INFN, Sezione di Perugia, I-62032, Camerino, Italy.
Abstract:
The experimental information on the observed nearly degenerate bands in the N = 75 isotones, in particular 134Pr and 136Pm, which are often considered as the best candidates for chiral bands, is critically analyzed. Most properties of the bands, in particular, the recently measured branching ratios and lifetimes, are in clear disagreement with the interpretation of the two bands as chiral bands. For I =14-18 in 134Pr, where the observed energies are almost degenerate, we have obtained a value of 2.0(4) for the ratio of the transition quadrupole moments of the two bands, which implies a considerable difference in the nuclear shape associated with the two bands. The insufficiency of the near-degeneracy criterion to trace nuclear chirality is emphasized.
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