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Assessment of Boron Doped Diamond Electrode Quality and Application to In Situ Modification of Local pH by Water Electrolysis
Published on: January 6, 2016
Tunneling spectroscopy and vortex imaging in boron-doped diamond
B Sacépé1, C Chapelier, C Marcenat
1DRFMC-SPSMS, CEA Grenoble, 17 rue des Martyrs, 38054 Grenoble Cedex 9, France. benjamin.sacepe@cea.fr
Physical Review Letters
|April 12, 2006
Summary
This study reveals superconductivity in boron-doped diamond using scanning tunneling spectroscopy below 100 mK. The material exhibits a superconducting gap and follows BCS theory, with unexpected localized states observed in vortex cores.
Area of Science:
- Condensed Matter Physics
- Materials Science
- Superconductivity
Background:
- Boron-doped diamond is a promising material for electronic applications.
- Understanding its superconducting properties is crucial for technological advancement.
- Previous studies have hinted at superconductivity, but detailed spectroscopic evidence was lacking.
Purpose of the Study:
- To investigate the superconducting properties of single-crystalline boron-doped diamond.
- To characterize the superconducting gap and its temperature dependence.
- To explore the behavior of vortices in this material.
Main Methods:
- Low-temperature scanning tunneling spectroscopy (LT-STS) performed below 100 mK.
- Measurement of the tunneling density of states.
- Vortex imaging using LT-STS in a low magnetic field.
Main Results:
- Observation of a distinct superconducting gap in the tunneling density of states.
- The temperature evolution of the superconducting order parameter aligns with weak-coupling Bardeen-Cooper-Schrieffer (BCS) theory, with Delta(0)/kBTc ≈ 1.74.
- Localized states were detected within vortex cores, which is unusual for a superconductor considered 'dirty'.
Conclusions:
- Single-crystalline boron-doped diamond exhibits clear signs of superconductivity.
- The material behaves as a weak-coupling superconductor according to BCS theory.
- The presence of localized states in vortex cores suggests complex physics beyond standard dirty superconductor models.

