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Updated: Aug 9, 2026
Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)
Published on: November 22, 2016
Bisphosphine based hetero-capsules for the encapsulation of transition metals
Tehila S Koblenz1, Henk L Dekker, Chris G de Koster
1Supramolecular and Homogeneous Catalysis, van 't Hoff Institute for Molecular Sciences, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands.
Abstract:
Just mixing of solutions of tetracationic diphosphine ligands and tetraanionic calix[4]arene building blocks leads to the formation of supramolecular heterocapsules that coordinate a palladium metal within the cavity of the assembly, giving rise to a new class of potential supramolecular transition metal catalysts.
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