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Nanoscale electrocrystallisation of Sb and the compound semiconductor AlSb from an ionic liquid
1Institute of Physical Chemistry, University of Karlsruhe (TH), Kaiserstrasse 12, D-76128 Karlsruhe, Germany.
Chemical Communications (Cambridge, England)
|April 13, 2006
Abstract:
Aluminium antimonide nanoclusters with an apparent band gap energy of 0.92 +/- 0.2 eV have been electrodeposited from the neutral ionic melt AlCl3-1-butyl-3-methylimidazolium chloride {AlCl3-[C4mim]+Cl-} at room temperature and have been characterized in-situ by electrochemical scanning tunneling microscopy (STM) and spectroscopy (STS).
