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Updated: Jul 12, 2026
09:25
Fabricating van der Waals Heterostructures with Precise Rotational Alignment
Published on: July 5, 2019
A nanoring-nanosphere molecule, {Mo214V30}: pushing the boundaries of controllable inorganic structural organization
Bogdan Botar1, Paul Kögerler, Craig L Hill
1Department of Chemistry, Emory University, Atlanta, Georgia 30322, USA.
Journal of the American Chemical Society
|April 20, 2006
Abstract:
A controlled, Raman-monitored chemical reduction of a molybdate and vanadate mixture affords a new type of molybdenum-oxide-based cluster showing an unprecedented level of inorganic structural organization. The cluster incorporates two nanosized substructures (a ring and a sphere) in an open clam-like assembly. Multiple methods indicate that the nanoring contains delocalized electrons and the nanosphere contains localized but interacting electrons.
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