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Synthesis and structural characterization of the first metal organic thallium antimonide

Stephan Schulz1, Florian Thomas, Martin Nieger

  • 1Department Chemie, Universität Paderborn, Warburger Strasse 100, J6.214, 33098 Paderborn, Germany. stephan.schulz@upb.de

Chemical Communications (Cambridge, England)
|April 20, 2006
PubMed

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Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
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Organometallic compounds are compounds that contain a carbon–metal bond. Carbon belongs to an organyl group like alkyl, aryl, allyl, or benzyl groups. The metal can be from Group I or Group II of the periodic table, a transition metal, or a semimetal.