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Updated: Aug 9, 2026

Electrochemically and Bioelectrochemically Induced Ammonium Recovery
Published on: January 22, 2015
Kinetics of aniline degradation by Fenton and electro-Fenton processes
Jin Anotai1, Ming-Chun Lu, Parichat Chewpreecha
1NRC for Environmental and Hazardous Waste Management, Department of Environmental Engineering, King Mongkut's University of Technology, Thonburi, Bangkok 10140, Thailand. jin.ano@kmutt.ac.th
Abstract:
Aniline degradation at pH 2 by Fenton and electro-Fenton processes was kinetically investigated in this study. Electro-Fenton process was found to be superior to ordinary Fenton process with the current impacts of 1.2 to 3.1 for removal efficiency and 1.2 to 5.8 for degradation rate depending on initial Fe2+ concentration. This is mainly due to the rapid electrochemical regeneration of Fe2+. Overall rate equations for aniline degradation by Fenton and electro-Fenton processes (in units of molar and minute) are: [EQUATION: SEE TEXT]. With current application, aniline degradation rate seems to be autonomous from Fenton's reagent concentrations and approaching a half order with respect to aniline. In addition, for complete removal of 0.01 M aniline, the delay in current supply at the initial stage could save up to one-third of the total energy required by the ordinary electro-Fenton process. As a result, significant reduction in energy consumption and operating cost could be obtained by the current-delay operating mode.
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