Intermolecular intersystem crossing in single-molecule spectroscopy: Terrylene in anthracene crystal

A Nicolet1, M A Kol'chenko, B Kozankiewicz

  • 1MoNOS, Huygens Laboratory, Leiden University, 2300 RA Leiden, The Netherlands.

Summary

We discovered a new relaxation pathway, matrix-enhanced intersystem crossing, in terrylene-doped anthracene crystals. This finding explains reduced single-molecule fluorescence and is crucial for developing new host-guest systems for spectroscopy.

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