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Synthesis of Monodisperse Cylindrical Nanoparticles via Crystallization-driven Self-assembly of Biodegradable Block Copolymers
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Effect of particle size, composition, and thermal treatment on the crystalline structure of polycaprolactone

Eun Chul Cho1, Kilwon Cho, Jong Kun Ahn

  • 1Skin Research Institute, Amorepacific Corporation/ R&D Center, 314-1, Bora-dong, Giheung-gu, Yongin, 446-729, Korea. emjo@amorepacific.com

Biomacromolecules
|May 9, 2006
PubMed
Abstract

No abstract available in PubMed .

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Polymer Classification: Crystallinity01:21

Polymer Classification: Crystallinity

Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...

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