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Di-mu-acetato-bis[(2-acetylpyridine thiosemicarbazonato)zinc(II)]

Emmanuel Ngwang Nfor1, Wei Liu, Jing-Lin Zuo

  • 1State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing 210093, People's Republic of China.

Acta Crystallographica. Section C, Crystal Structure Communications
|May 9, 2006
PubMed

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Arenediazonium substitution reactions occur when the diazonium group is substituted by various functional groups such as halides, hydroxyl, nitrile, etc. For instance, arenediazonium salts react with copper(I) salts of chloride, bromide, or cyanide to form corresponding aryl chlorides, bromides, and nitriles. These reactions are named Sandmeyer reactions. Although the mechanism of this reaction is complicated, as illustrated in Figure 1, they are believed to progress via an aryl copper...