Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

Local and chain dynamics in miscible polymer blends: A Monte Carlo simulation study.

Jutta Luettmer-Strathmann1, Manjeera Mantina

  • 1Department of Physics and Department of Chemistry, The University of Akron, Akron, Ohio 44325-4001, USA. jutta@physics.uakron.edu

The Journal of Chemical Physics
|May 13, 2006
PubMed
Summary

Polymer blend dynamics were simulated using Monte Carlo methods. The study found that reduced diffusion coefficients and chain lengths collapse onto a common line, offering insights into polymer friction.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Dependence of the polymer adsorption transition on chain stiffness and surface interaction range: A partition-function-zero analysis.

Physical review. E·2025
Same author

Partition-function-zero analysis of polymer adsorption for a continuum chain model.

Physical review. E·2021
Same author

Five-Site Model for Brownian Dynamics Simulations of a Molecular Walker in Three Dimensions.

The journal of physical chemistry. B·2021
Same author

Thermodiffusion of aqueous solutions of various potassium salts.

The Journal of chemical physics·2021
Same author

Configurational contribution to the Soret effect of a protein ligand system : An investigation with density-of-states simulations.

The European physical journal. E, Soft matter·2019
Same author

Partition function zeros and finite size scaling for polymer adsorption.

The Journal of chemical physics·2014

Area of Science:

  • Polymer Science
  • Computational Chemistry
  • Materials Science

Background:

  • Local chain structure and environment significantly influence polymer dynamics in miscible blends.
  • Friction coefficients in blends typically differ from those in pure polymer melts.

Purpose of the Study:

  • To investigate polymer blend dynamics using Monte Carlo simulations.
  • To explore the relationship between chain length, local mobility, and self-diffusion coefficients.
  • To analyze the composition and pressure dependence of friction coefficients in polymer blends.

Main Methods:

  • Utilized Monte Carlo simulations with a generalized bond fluctuation model.
  • Incorporated differences in interaction energies to distinguish blend components.
  • Employed local moves and a no bond crossing condition for simulations.

Related Experiment Videos

  • Calculated characteristic chain lengths and local mobilities to determine self-diffusion coefficients.

    • Main Results:

    • Data for polymer melts and blends collapsed onto a common line when plotting reduced diffusion coefficients against reduced chain length.
    • Friction coefficients were calculated from local mobilities, showing dependence on composition and pressure.
    • The simulated friction coefficients exhibited characteristics consistent with experimental observations in miscible polymer blends.

    Conclusions:

    • The generalized bond fluctuation model effectively captures polymer blend dynamics.
    • A universal scaling relationship exists between reduced diffusion coefficients and reduced chain lengths.
    • The simulation approach provides a valuable tool for understanding and predicting the behavior of miscible polymer blends.