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Updated: Aug 8, 2026

Using Cyclic Voltammetry, UV-Vis-NIR, and EPR Spectroelectrochemistry to Analyze Organic Compounds
Published on: October 18, 2018
Effect of sample preparation and excitation conditions on the single molecule spectroscopy of conjugated polymers
Young Jong Lee1, Doo Young Kim, Paul F Barbara
1Center for Nano- and Molecular Science and Technology and Department of Chemistry and Biochemistry, University of Texas at Austin, 78712, USA.
Abstract:
Extensive new single molecule spectroscopy (SMS) data on the conjugated polymer MEH-PPV at low temperature were obtained. In particular, the combined effects of sample preparation and excitation condition were explored in detail. The data confirm previous observations from this laboratory that (i) the distribution of emission maxima of single MEH-PPV molecules has a bimodal distribution and (ii) the single molecule emission spectrum of MEH-PPV exhibits few time-dependent fluctuations of the emission intensity, band shape, or spectral maxima. These data also help explain the discrepancy among the various published SMS data on this compound and suggest that environmental impurities, long irradiation times, nearby interfaces, and incomplete data sampling may account for some of the discrepancies among the published data.
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