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Three ent-trachylobane diterpenes from the leaf exudates of Psiadia punctulata

Bernard F Juma1, Jacob O Midiwo, Abiy Yenesew

  • 1Department of Chemistry, University of Nairobi, P O Box 30197, Nairobi, Kenya.

Phytochemistry
|June 13, 2006
PubMed

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Aromatic Hydrocarbon Cations: Structural Overview01:18

Aromatic Hydrocarbon Cations: Structural Overview

Cycloheptatriene is a neutral monocyclic unsaturated hydrocarbon that consists of an odd number of carbon atoms and an intervening sp3 carbon in the ring. The three double bonds in the ring correspond to 6 π electrons, which is a Huckel number, and therefore satisfies the criteria of 4n + 2 π electrons. However, the intervening sp3 carbon disrupts the continuous overlap of p orbitals. As a result, cycloheptatriene is not aromatic.
Removing one hydrogen from the intervening CH2 group with both...